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  skos:definition """Research Objectives of the Investigation of Sulfur Chemistry in
 Antarctic Troposphere (ISCAT):


 During this four-year study at Amundsen-Scott South Pole
 Station, we will examine the sulfur chemistry of the Antarctic
 atmosphere. The study involves two field seasons, the first of
 which was completed in 1998-1999. This field season (2000-2001)
 will be the second and last for this project. The study, which
 includes 10 principal and senior investigators at five
 institutions, with seven additional contributing investigators,
 has two broad-based goals: to improve substantially our current
 understanding of the oxidation chemistry of bioorganic sulfur
 in the polar environment, and to improve the climatic
 interpretation of sulfur-based signals in Antarctic ice-core
 records.

 The South Pole was selected because the atmospheric boundary
 layer at this site presents a homogeneous and relatively simple
 environment from which to unravel the photochemically driven
 oxidation chemistry of dimethyl sulfide. Atmospheric sulfur
 chemistry is an important component in climate change issues
 because both naturally (i.e., from volcanic emissions and
 oceanic phytoplankton production) and anthropogenically emitted
 sulfur compounds form minute particles in the atmosphere--the
 so-called aerosols--that reflect solar radiation, produce
 atmospheric haze and acid rain, and affect ozone
 depletion. Sulfate particles in the atmosphere may also act as
 condensation nuclei for water vapor and enhance global
 cloudiness. On the millennial time scale, the variability and
 natural background level of atmospheric aerosols can be
 reconstructed from the preserved paleorecords of sulfur
 oxidation products in ice cores. It is necessary, however, to
 understand how the physical and chemi!  cal environment of the
 oxidation process affects the relative concentrations of the
 oxidation products that become buried in the ice. This study
 requires simultaneous observations of a wide-ranging suite of
 sulfur species, such as DMS and its oxidation products, sulfur
 dioxide, dimethyl sulfoxide, dimethyl sulfone, methane sulfonic
 acid, and sulfuric acid, as well as photochemically important
 compounds such as carbon monoxide, nitrous oxide, water vapor,
 and non-methane hydrocarbons.

Secondary objectives will be:

to examine interior Antarctic air samples for other significant
DMS oxidation products, such as sulfurous acid and methane
sulfonic acid; and to assess the local variation in hydroxyl and
perhydroxyl radicals, a measure of the oxidizing power of the
atmosphere.  This study will provide, for the first time, a
quantitative picture of exactly which atmospheric sulfur
compounds are advected into the Antarctic interior and a
detailed picture of the sulfur chemistry that is active in the
Antarctic atmosphere.

Contact Information:

Dr. Douglas Davis, Principal Investigator

Georgia Institute of Technology
School of Earth and Atmospheric Sciences
221 Bobby Dodd Way
Atlanta, GA 30332-0340

Phone: 404-894-4008
Fax: 404-894-1993
Email: douglas.davis&#64eas.gatech.edu

For more information,
link to
"http://rpsc.raytheon.com/science/SciPlanSummaries/sps00/00_OO_270_O.htm"

[Summary provided by Raytheon]"""@en ;
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